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The formation of ettringite in the fresh, plastic concrete is the mechanism that controls stiffening. Ettringite is a primary constituent of hydration of Portland cement concrete. Its formation plays an important role in the control of setting. Minor amounts of secondary ettringite are often encountered in air voids of hardened concretes, regardless of the type of cement used. In concrete chemistry ettringite is a hexacalcium aluminate trisulfate hydrate, of general formula: (CaO) 6 (Al 2 O 3)(SO 3) 3 ·32H 2 O. or (CaO) 3 (Al 2 O 3)(CaSO 4) 3 ·32H 2 O. Ettringite is formed in hydrated Portland cement system as a result of the reaction of calcium aluminate with calcium sulfate, both present in Portland cement. An ettringite formation in hardened concrete does not in every case lead to a direct damage of the concrete structure.
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Reasons for the apparent newness of the phenomenon, and Delayed ettringite formation (DEF) occurs at late ages and the related heterogeneous expansion in a very rigid hardened concrete can produce cracking and spalling. Two different types of DEF are examined depending on the sulfate source: DEF caused by external sulfate attack (ESA) or internal sulfate attack (ISA). An experimental study is conducted to investigate the effect of a range of parameters on concrete expansion and premature deterioration associated with delayed ettringite formation (DEF). These parameters were identified from a comprehensive literature review; they include concrete curing conditions and cement chemistry. Ettringite formation is associated with expansion and many hypotheses of ettringite related expansion have been advanced (2-4).
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OSTI.GOV Journal Article: Preferred orientation of ettringite in concrete fractures. Preferred orientation of ettringite in concrete fractures Delayed Ettringite Formation in Fly Ash Concrete under Moist Curing Conditions. During the hydration of cement, tricalcium aluminate (C 3 A) reacts with gypsum and forms ettringite (AFt). Once all gypsum is consumed, ettringite can further react with remaining C 3 A and form monosulfate (AFm) at 1–2 days.
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Most of the sulfate in the cement is normally consumed to form ettringite at early ages. The formation of ettringite in the fresh, plastic concrete is the mechanism that controls stiffening.
The growth of ettringite crystals and associated morphological changes induce excessive expansion pressure inside the hardened concrete …
2016-5-31 · ettringite occurs in a plastic concrete and does not produce any significant stress. Another example of harmless and usefulEEF is Type expansive K cement containing a calcium aluminate sulfate (C4A3S) which, under proper restraint, hydrates within a …
2014-5-22 · mineral ettringite (a hydrated calcium sulfoaluminate) which is a normal product of early cement hydration. oDEF is a result of high early temperatures (above 70 o C – 80 C) in the concrete caused either by application of accelerated (heat) curing or by the build-up of
2018-11-1 · termed "secondary ettringite forma-tion," but because that phrase has an other meaning to most petrographers, the more definitive term "delayed et tringite formation," or simply DEF, was coined. DEF is the development of ettringite within the cement paste system of concrete after the concrete has hardened. The result is expansion,
1998-8-10 · Secondary ettringite formation (SEF) is a problem that adversely affects the durability of Portland cement concrete. Secondary ettringite formation in concrete is a relatively recent phenomenon.
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Consequently Secondary gypsum, ettringite, and thaumasite, as well as several sulfate efflorescence have been detected.
Delayed ettringite formation (DEF) occurs at late ages and the related heterogeneous expansion in a very rigid hardened concrete can produce cracking and spalling. Two different types of DEF are examined depending on the sulfate source: DEF caused by external sulfate attack (EM) or internal sulfate attack (ISA). Ettringite is also known as c ement bacillus, which is the name of a naturally occurring mineral of the same composition and structure.
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Ettringite is formed in hydrated Portland cement system as a result of the reaction of calcium aluminate with calcium sulfate, Gypsum and other sulfate compounds react with calcium aluminate in the cement to form ettringite within the first few hours after mixing with water. Most of the sulfate in the cement is normally consumed to form ettringite at early ages. The formation of ettringite in the fresh, plastic concrete is the mechanism that controls stiffening. Ettringite is a primary constituent of hydration of Portland cement concrete.
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Ettringite is a normal product of early Ettringite Group.
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Fine aggregates and sand tend to trap air bubbles, and a stiff cement paste won't allow the PosiTector CMM IS In Situ Concrete Moisture Meter is the simple, durable, and accurate way to perform concrete moisture testing in accordance with ASTM 14 Jun 2014 Delayed ettringite formation is a consequence of improper heating during the curing process. It is a normal product in concrete and is delayed % calcium aluminate cement, 25 wt.% Portland cement and 25 wt.% calcium sulfate were studied (w/c= 1). The calcium sulfate was beta-hemilrydrate, anhydrite Concrete sleepers cracked due to delayed ettringite formation have been exposed to fatigue loading. The applied load has been varied av L Elfgren · 2003 — Concrete sleepers cracked due to delayed ettringite formation have been exposed to fatigue loading.
This paper investigates the influence of cement and limestone filler (LF) particle size on self-consolidating concrete expansion due to delayed ettringite formation. LF was used to replace 15% of the cement. All concrete mixtures had 5% silica fume and a water-cement ratio (w/c) of 0.34. 2000-12-1 Delayed ettringite formation (DEF) occurs at late ages and the related heterogeneous expansion in a very rigid hardened concrete can produce cracking and spalling. Two different types of DEF are examined depending on the sulfate source: DEF caused by external sulfate attack (EM) or … 2021-1-4 · When concrete returns to ambient temperature and absorbs water from the external environment, ettringite regenerates. The growth of ettringite crystals and associated morphological changes induce excessive expansion pressure inside the hardened concrete … 2016-5-31 · ettringite occurs in a plastic concrete and does not produce any significant stress. Another example of harmless and usefulEEF is Type expansive K cement containing a calcium aluminate sulfate (C4A3S) which, under proper restraint, hydrates within a … 2014-5-22 · mineral ettringite (a hydrated calcium sulfoaluminate) which is a normal product of early cement hydration.